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He was a member of the Brazilian teams which won the 2013 FIFA Confederations Cup and reached the semi-finals of the 2014 FIFA World Cup.
At the worst situation of its history, in the third division, the club eventually promoted to the second level after finishing in second position, with the player appearing in eight of the club's last decisive nine games, He made a somewhat tumultuous debut for the club in a UEFA Cup match against Paris Saint-Germain at the Parc des Princes, partnering compatriot Anderson in the center of the defence, replacing the injured Luisão.
He joined Chelsea in January 2011, winning the Champions League and the FA Cup in the following season.
In June 2014, he transferred to Paris Saint-Germain for a fee of £50 million (€62 million), a world record transfer for a defender, David Luiz made his full international debut in 2010 and has since earned over 50 caps.
On 11 January 2009, David Luiz netted his first official goal for Benfica, the game's only in a home success against Braga.